(Trimethylsilyl)methylmagnesium chloride, 1.1M solution in THF

Name	(trimethylsilyl)methylmagnesium chloride
Synonyms	TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Trimethylsilylmethylmagnesium chloride (trimethylsilyl)methylmagnesium chl. sol (trimethylsilyl)methylmagnesium chloride [(trimethylsilyl)methyl]magnesium(1+) chloride (TRIMETHYLSILYL)METHYLMAGNESIUM CHL. SOL , 1 M IN DIETH.ETHER (Trimethylsilyl)methylmagnesium chloride, 1.1M solution in THF [(Trimethylsilyl)methyl]magnesium Chloride 1.0 M In Diethyl Ether [(Trimethylsilyl)methyl]magnesium Chloride, 1.0 M In Tetrahydrofuran (TRIMETHYLSILYLMETHYL)MAGNESIUM CHLORIDE , 1.0M SOLUTION IN DIETHYL ETHER
CAS	13170-43-9
InChI	InChI=1/C4H11Si.ClH.Mg/c1-5(2,3)4;;/h1H2,2-4H3;1H;/q;;+1/p-1/rC4H11MgSi.ClH/c1-6(2,3)4-5;/h4H2,1-3H3;1H/q+1;/p-1

Molecular Formula	C4H11ClMgSi
Molar Mass	146.97
Density	1.04
Melting Point	105.8-106.4 °C
Flash Point	-40°C
Solubility	Sol ethereal solvents; reacts with protic solvents.
Appearance	Low Melting Solid
Specific Gravity	0.912
Color	Clear colorless to yellow to greenish
BRN	3587255
Storage Condition	Flammables + water-Freezer (-20°C)e area
Sensitive	8: reacts rapidly with moisture, water, protic solvents

Risk Codes	R12 - Extremely Flammable R14 - Reacts violently with water R22 - Harmful if swallowed R34 - Causes burns R66 - Repeated exposure may cause skin dryness or cracking R67 - Vapors may cause drowsiness and dizziness R19 - May form explosive peroxides R11 - Highly Flammable
Safety Description	S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.) S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
UN IDs	UN 3399 4.3/PG 1
WGK Germany	1
FLUKA BRAND F CODES	10
TSCA	No
HS Code	29319090
Hazard Class	8
Packing Group	II

Uses	Various nickel catalytic reaction reagents, including the enylation reaction of dithioacetal, cross-coupling reaction of trifluoromethyl sulfonate aryl ester and carbamate, and cross-coupling reaction of vinyl selenoether.

Last Update：2024-04-10 22:29:15

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